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Here are abstracts from Volume 5 Number 1 of the Journal
of the Swimming Pool and Spa Industry:
Benjamin D. Tanner and Charles P. Gerba, Ph.D.
Department of Microbiology and Immunology, and Department of Soil, Water,
and Environmental Science University of Arizona
Application of the Ct Concept for Determining the
Disinfection of Microorganisms in Water
Recreational waters such as swimming pools and hot tubs are a potential
source of microbial disease transmission among children and adults. In
order to control disease transmission it is necessary to maintain an adequate
level of chemical disinfectant. To accomplish this, the Ct concept can be
used, where C is the disinfectant concentration and t the time required
to inactivate a certain percentage of microorganisms in water. The multiplication
of the two values produces a number which assesses the efficiency of a disinfectant.
Ct allows for comparison of disinfectant effectiveness in general and with
respect to different microbes or water conditions. The Ct concept, when
applied to the disinfection of recreational waters, helps professionals
in the field determine the amount of disinfectant needed to control pathogenic
microorganisms in water and prevent the spread of disease.
John A. Wojtowicz
Chemcon
Effect of Cyanuric Acid on Swimming Pool Maintenance
Cyanuric acid is added to swimming pools to reduce photochemical decomposition
of free available chlorine (av. Cl) by ultraviolet (UV) rays in sunlight.
This is accomplished by formation of chloroisocyanyurates that do not appreciably
absorb UV light. Recent data show that the av. Cl loss rate caused by sunlight
is only about 1% per day at 138 ppm CA. This is consistent with the fact
that over 99% of the av. Cl in CA stabilized pools is in the form of chloroisocyanurates.
Virtually all of the decomposition (about 14% per day) observed in a bather-free
pool in the summer time in the Phoenix area is due to thermal decomposition
of chloroisocyanurates. Bather load can appreciably increase the av. Cl
loss rate. Cyanuric acid, in combination with its ionized form (ie, cyanurate
ion), also functions as a buffer to help stabilize pH.
John A. Wojtowicz
Chemcon
Sanitizer and Oxidizer Product Information Summaries
Summary sheets containing product description, properties, and performance
data for various sanitizers, oxidizers, and sanitation systems shown below
are based on the following published papers:
Wojtowicz, J. A., "Survey of Swimming Pool/Spa Sanitizers and Sanitation
Systems", Journal of the Swimming Pool and Spa Industry 4(1)2001:9
-29.
Wojtowicz, J. A., "Use of Ozone in the Treatment of Swimming Pools
and Spas", Journal of the Swimming Pool and Spa Industry 4(1)2001:41
- 53.
Some of the categories covered in the summaries include: disinfection,
algae control, oxidation of contaminants, cost, and cost effectiveness.
1. Chlorine
2. Bromine
3. Ozone: Data on Disinfection and Oxidation
4. Ultraviolet (UV) Ozone
5. Corona Discharge (CD) Ozone (DIN Design)
6. Corona Discharge (CD) Ozone (Modified DIN Design)
7. Copper, Silver, and Zinc
8. Copper-Silver Ionizers
9. Copper-Silver Cartridges
10. Zinc-Silver Cartridges
11. Potassium Monopersulfate
12. Potassium Peroxydisulfate (Persulfate)
13. Polyhexamethylene Biguanide (PHMB)
14. Ultraviolet Light (UV) and Hydrogen Peroxide
John A. Wojtowicz
Chemcon
Swimming Pool and Spa Water Chemical Adjustments
This paper deals with adjustments to swimming pool and spa water chemical
parameters such as pH, alkalinity, hardness, stabilizer, and chlorine.
It discusses test kit acid and base demand tests and provides equations
for calculating required acid and base additions for adjusting pH based
on the test results. It also discusses a mathematical approach for calculating
acid and base additions (and associated alkalinity changes) and pH changes
resulting from addition of sodium bicarbonate (for alkalinity adjustment)
and cyanuric acid (for stabilizer adjustment) based on swimming pool chemical
equilibria. Tables, graphs, and a general equation are provided for determining
required acid and base additions for adjusting pH. In addition, equations
are provided for determining required chemical additions for adjusting alkalinity,
hardness, stabilizer, and chlorine concentrations.
Kim Skinner
onBalance
The Total Dissolved Solids Contributions of Various
Swimming Pool and Spa Balancing Compounds
The amount of total dissolved solids (TDS) contributed by certain swimming
pool and spa balancing chemicals has been misreported in various publications
of trade liturature. The correct contributions, as well as the calculations
used to arrive at these figures, and the rationale which explains the errors,
are dilineated.
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